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In a recent Journal of the American Chemical Society (JACS) communication, two members of the Gagliardi group, graduate student Chad Hoyer and post-doctorate Giovanni Li Manni, computationally characterized an unprecedented two-coordinate, high-spin Mn(0) complex.

…of Cardiff University. The molecule has been experimentally shown to behave as an “inorganic Grignard reagent” in the preparation of the first two-coordinate Mn(I) dimer and a heterobimetallic Mn(II)-Cr(0) complex….